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Maleic Acid: Properties, Applications and Safety Overview

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Maleic acid, a dicarboxylic unsaturated organic acid, is an important industrial chemical with wide-ranging applications. This article examines its key characteristics, commercial uses, and handling precautions.

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Table 1: Physical and Chemical Properties

PropertySpécification
Formule moléculaireC₄H₄O₄
Molecular Weight116.07 g/mol
ApparencePoudre cristalline blanche
Point de fusion130-135°C
Solubility (25°C)Water: 478 g/L; Ethanol: 63 g/L
pKa ValuespKa1=1.9; pKa2=6.07
IsomerCis-form of butenedioic acid

Maleic acid exhibits higher acidity and solubility compared to its trans-isomer (fumaric acid), making it more reactive in chemical processes.

Table 2: Major Industrial Applications

IndustryApplicationFunction
PolymerProduction of unsaturated polyester resinsCrosslinking agent
FoodAcidulant (limited use)pH regulator
AgricultureHerbicide intermediateChelating agent
TextileDye and pigment manufacturingIntermediate
PharmaceuticalSynthesis of active ingredientsPrecursor

The polymer industry accounts for approximately 65% of global maleic acid consumption, primarily for resin production.

Table 3: Safety and Handling Guidelines

ParameterSpécification
OSHA PEL1 mg/m³ (8-hr TWA)
Point d'éclairNon-flammable
Storage ConditionsKeep in cool, dry place below 30°C
First Aid MeasuresFlush eyes/skin with water if contacted
Environmental ImpactReadily biodegradable (OECD 301D)

Key Technical Considerations:

  • Readily undergoes addition reactions at the double bond
  • Forms anhydride at temperatures above 140°C
  • Exhibits strong chelating properties
  • Serves as precursor for malic, fumaric, and tartaric acids

Recent market trends show:

  • Growing demand for maleic anhydride derivatives
  • Development of bio-based production methods
  • Increased use in water treatment chemicals

Global production exceeds 1.8 million metric tons annually, with Asia-Pacific being the dominant manufacturing region. Future applications may expand in sustainable material development and specialty chemicals.

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