BINAP 1.1′-Binaphthyl-2.2′-diphemyl phosphine CAS 98327-87-8

Synonymes

BINAP
Binap
(?-Binap
1.1′-Binaphthyl-2.2′-Diphemyl Phosphine
2,2′-BIS(DIPHENYLPHOSPHINO)-1,1′-BINAPHTHYL
(?-2,2-Bis(Diphenylphosphino)-1,1-Binaphthyl
Rac-2,2-Bis(Diphenylphosphino)-1,1-Binaphthyl
2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene
Racemic-2,2′-bis(diphenylphosphino)-1,1′-binaphthy
racemic-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl
S(-)-(1,1′-Binaphthalene-2,2′-Diyl)Bis(Diphenylphosphine)
RACEMIC-2,2”-BIS(DIPHENYLPHOSPHINO)-1,1”-BINAPHTHYL BINAP
2,2′-Bis-(diphenylphosphino)-1,1′-binaphthyl (Racemic BINAP)

CAS

98327-87-8

EINECS

619-338-0

Inchikey

MUALRAIOVNYAIW-UHFFFAOYSA-N

Masse molaire

622.69

Point de fusion

283-286°C(lit.)

point Boling

724.3±55.0 °C(Predicted)

Solubilité dans l'eau

Soluble in tetrahydrofuran, benzene and dichloromethane. Slightly soluble in ether, methanol and ethanol. Insoluble in water.

Solubilité

Chloroform (Slightly, Sonicated), Dichloromethane (Slightly, Heated),

Apparence

White to beige powder

Couleur

White to light beige

Merck

14,1223

BRN

5321443

Condition de stockage

Garder dans un endroit sombre, atmosphère inerte, température ambiante

Sensible

Sensible à l'air

MDL

MFCD00010805

Propriétés physiques et chimiques

Melting point 280-285°C.

Utilisation

Used for asymmetric hydrogenation catalysis, carbonyl reduction, etc. A ligand for the palladium-catalyzed arylamine coupling reaction for the preparation of desmethylthio-colchicine? cicatine. It can be used in combination with Cu(II) to catalyze the addition reaction of arylsulfonamide to produce styrene and olefins. It can also be used for palladium-catalyzed tripyridyl amine reaction.

Codes de risque

36/37/38 – Irritating to eyes, respiratory system and skin.

Description de la sécurité

S22 – Do not breathe dust.
S24/25 – Avoid contact with skin and eyes.
S37/39 – Wear suitable gloves and eye/face protection
S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Wgk Allemagne

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