Nameracemic-2,2'-Bis(diphenylphosphino)-1,1'-binaphthylSynonymsBINAPBinap(?-Binap1.1'-Binaphthyl-2.2
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| Nom | racemic-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl |
| Synonymes | BINAP Binap (?-Binap 1.1'-Binaphthyl-2.2'-Diphemyl Phosphine 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL (?-2,2-Bis(Diphenylphosphino)-1,1-Binaphthyl Rac-2,2-Bis(Diphenylphosphino)-1,1-Binaphthyl 2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene Racemic-2,2'-bis(diphenylphosphino)-1,1'-binaphthy racemic-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl S(-)-(1,1'-Binaphthalene-2,2'-Diyl)Bis(Diphenylphosphine) RACEMIC-2,2''-BIS(DIPHENYLPHOSPHINO)-1,1''-BINAPHTHYL BINAP 2,2'-Bis-(diphenylphosphino)-1,1'-binaphthyl (Racemic BINAP) |
| CAS | 98327-87-8 |
| EINECS | 619-338-0 |
| Inchikey | MUALRAIOVNYAIW-UHFFFAOYSA-N |
| Formule moléculaire | C44H32P2 |
| Masse molaire | 622.69 |
| Point de fusion | 283-286°C(lit.) |
| point Boling | 724.3±55.0 °C(Predicted) |
| Solubilité dans l'eau | Soluble in tetrahydrofuran, benzene and dichloromethane. Slightly soluble in ether, methanol and ethanol. Insoluble in water. |
| Solubilité | Chloroform (Slightly, Sonicated), Dichloromethane (Slightly, Heated), |
| Apparence | White to beige powder |
| Couleur | White to light beige |
| Merck | 14,1223 |
| BRN | 5321443 |
| Condition de stockage | Garder dans un endroit sombre, atmosphère inerte, température ambiante |
| Sensible | Sensible à l'air |
| MDL | MFCD00010805 |
| Propriétés physiques et chimiques | Melting point 280-285°C. |
| Utilisation | Used for asymmetric hydrogenation catalysis, carbonyl reduction, etc. A ligand for the palladium-catalyzed arylamine coupling reaction for the preparation of desmethylthio-colchicine? cicatine. It can be used in combination with Cu(II) to catalyze the addition reaction of arylsulfonamide to producUsed for asymmetric hydrogenation catalysis, carbonyl reduction, etc. A ligand for the palladium-catalyzed arylamine coupling reaction for the preparation of desmethylthio-colchicine? cicatine. It can be used in combination with Cu(II) to catalyze the addition reaction of arylsulfonamide to produce styrene and olefins. It can also be used for palladium-catalyzed tripyridyl amine reaction.e styrene and olefins. It can also be used for palladium-catalyzed tripyridyl amine reaction. |
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